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Stable chlorine isotopic signatures and fractionation mechanism of groundwater in Anyang, China

Tong Xiao-xia Gan Rong Gu Shu-qian Sun Xing-le Huang Kai-tuo Yan Xiao-feng

Tong XX, Gan R, Gu SQ, et al. 2022. Stable chlorine isotopic signatures and fractionation mechanism of groundwater in Anyang, China. Journal of Groundwater Science and Engineering, 10(4): 393-404 doi:  10.19637/j.cnki.2305-7068.2022.04.007
Citation: Tong XX, Gan R, Gu SQ, et al. 2022. Stable chlorine isotopic signatures and fractionation mechanism of groundwater in Anyang, China. Journal of Groundwater Science and Engineering, 10(4): 393-404 doi:  10.19637/j.cnki.2305-7068.2022.04.007

doi: 10.19637/j.cnki.2305-7068.2022.04.007

Stable chlorine isotopic signatures and fractionation mechanism of groundwater in Anyang, China

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  • Figure  1.  Geological map of the study area and distribution of sampling points

    Figure  2.  Correlation between groundwater Cl concentration and δ37Cl values

    Figure  3.  Relationship between δ18O and δD values of groundwater

    Figure  4.  δ37Cl-δ18OH2O relationship

    Figure  5.  δ37Cl-δDH2O relationship

    Figure  6.  Relationship between groundwater Cl ion concentration and burial depth

    Figure  7.  Relationship between groundwater δ37Cl value and burial depth

    Figure  8.  (a) Relationship between Cl and δ37Cl values in pore pressurized water of the Quaternary system (b) Conceptual illustration of ion permeation. 034 (0.21, 105.5) indicates point 034 (δ37Cl, Cl) , respectively

    Table  1.   Results of chemical compositions and isotope of groundwater in the Anyang area

    001Beishan Village 1120Karst water16.10.25−8.06−60.7
    002Beishan Village120Karst water15.90.30−8.36−62.6
    003Xi-quyang160Karst water41.50.29−7.47−58.6
    004Shangtao Village25Quaternary13.40.03−8.22−63.0
    005Shang-yanke185Karst water28.20.07−7.91−61.7
    006Redflag canalCCanal water52.10.48−7.80−62.0
    007Redflag canalspSpring water10.60.04−8.78−64.5
    008Jian VillagespSpring water10.50.20−8.43−61.3
    009Guojia VillagespSpring water8.6−0.26−9.59−65.9
    011Beiqu Ditch40Quaternary87.40.12−7.55−57.4
    012Pearl-springspSpring water14.90.15−8.31−64.1
    013Jishan Village 115Quaternary89.10.32−7.74−60.8
    014Jishan Village 220Karst water17.00.49−8.27−63.4
    015Gutuo Village6Quaternary146.50.56−7.16−54.4
    016Zhongle Village10Quaternary23.10.02−7.64−61.2
    017Shaojia Tun40Quaternary37.90.65−7.52−58.8
    018Biaojian Village19Quaternary85.30.13−7.97−61.2
    020Geological seven70Quaternary130.40.20−7.61−60.0
    021Xiao-nanhaispSpring water22.30.35−7.89−62.6
    022Zhang er Village13Karst water15.70.35−8.41−62.2
    023Xiabao Village20Karst water16.70.60−8.32−63.0
    024Tielu Village20Karst water16.50.11−8.33−62.2
    025Xiao-tun Village17Karst water16.00.17−8.50−64.2
    026Guojiayuan18Karst water23.60.13−7.92−61.0
    027Xiaodian Village18Karst water20.00.12−8.41−63.0
    028Bei-xiangkou19karst water20.90.27−8.47−63.4
    030Beiwu Village30Quaternary48.70.20−10.0−75.6
    031Fengsu Village40Quaternary85.30−7.28−56.0
    032Lu Villge70Quaternary154.80.14−8.69−66.3
    034Dudian Village40Quaternary105.50.21−8.30−63.0
    037Gaojia Village20Quaternary33.1−0.14−7.70−61.5
    038Ma-toujian Village70Quaternary52.60.19−8.33−64.6
    下载: 导出CSV

    Table  2.   The measured chlorine isotope values of the Bohai Sea and the Yellow Sea

    Sampling locationSampling time(year)Measured
    δ37Cl (‰)
    The Bohai seaPeitaiho20100.06
    Peitaiho (500 m from the shore)2010−0.10
    Huanghua City, Hebei Province2010−0.08
    Yellow SeaYantai, Shandong19950.00
    The East China SeaShanghai2010−0.01
    Notes: ISL-354 seawater was used as the standard (Xiao et al. 2007)
    下载: 导出CSV
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  • 收稿日期:  2022-07-20
  • 录用日期:  2022-11-04
  • 网络出版日期:  2022-12-27
  • 刊出日期:  2022-12-31