Groundwater quality evaluation for irrigation using irrigation water quality indexes under GIS framework in Aksum Area, Northern Ethiopia
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Abstract: This study evaluates the suitability of irrigation water in the semi-arid region of Aksum, northern Ethiopia. An integrated approach combining the Irrigation Water Quality Index (IWQI) and ArcGIS-based spatial analysis was applied to assess the spatial variability of irrigation water quality. Twenty-five groundwater samples were collected and analyzed for key physicochemical parameters and heavy metals using standard laboratory techniques. Exceedances of recommended irrigation water limits were recorded for magnesium (16%), nitrate (32%), salinity hazard (12%), total dissolved solids (20%), total hardness (60%), residual sodium carbonate (16%), kelly index (4%), and magnesium ratio (32%). Based on the Irrigation Water Quality Index (IWQI), 36% of the samples fell under high restriction, 32% under moderate restriction, 24% under severe restriction, and 8% under low restriction for irrigation use. Although most of groundwater sources are suitable based on individual water quality parameters, the IWQI indicates that a significant portion of samples requires restricted use for irrigation. This highlights the need for targeted groundwater management strategies to mitigate localized risks associated with salinity and sodicity. The integrated IWQI-GIS approach demonstrated in this study is readily transferable to other arid and semi-arid regions, providing a robust tool for sustainable irrigation management and climate-resilient agricultural planning.
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Figure 9. Classification of water samples based on salinity (EC) and sodium hazard (according to Wilcox, 1955)
Figure 10. Spatial distribution of irrigation water quality parameters in the study area
Notes: Including electrical conductivity (EC), total dissolved solids (TDS), total hardness (TH), sodium adsorption ratio (SAR), residual sodium carbonate (RSC), sodium percentage (Na%), Kelly index (KI), permeability index (PI), magnesium ratio (MR), and potential salinity (PS). The corresponding classification criteria and suitability classes are indicated in the legend.
Figure 11. Wilcox's (1955) diagram showing the relation between sodium percent and salinity hazard (EC)
Figure 12. Doneen diagram of permeability index against the total concentration of ions (Doneen, 1975)
Table 1. Parameters, equations, and irrigation suitability classes used in the study area
Parameters Equations Range Classification References EC (µS/cm) <250 Excellent Richards (1954) 250–750 Good 750–2,250 Permissible 2,250–4,000 Doubtful TDS (mg/L) <1,000 Non-saline Robinove et al. (1958) 1,000–3,000 Slightly saline 3,000–10,000 Moderately saline >10,000 Very saline TH (mg/L) <75 Soft Vasanthavigar (2013) 75–150 Moderate 150–300 Hard >300 Very hard SAR (meq/L) $ {(\text{Na}}^{+})/\sqrt{{[(\text{Ca}}^{2+}+{\text{Mg}}^{2+})/2]} $ <10 Excellent Richards (1954) 10–18 Good 18–26 Doubtful >26 Unsuitable RSC (meq/L) (HCO3−+CO32−)-(Ca2++Mg2+) <1.25 Good Richards (1954) 1.25–2.5 Medium >2.5 Unsuitable Na% $ [({\text{Na}}^{+}+{\mathrm{K}}^{+})/({\text{Ca}}^{2+}+{\text{Mg}}^{2+}+{\mathrm{K}}^{+}+{\text{Na}}^{+})]\times 100 $ <20 Excellent Wilcox (1955) 20–40 Good 40–60 Permissible 60–80 Doubtful >80 Unsuitable KI (meq/L) $ [({\text{Na}}^{+})/{\text{Ca}}^{2+}+{\text{Mg}}^{2+})] $ <1 Suitable Kelly (1963) >1 Unsuitable PI% $ \left[\left[{\text{Na}}^{+}+\sqrt{{{{\text{HCO}}_{3}}}^{-}]}/{\text{Ca}}^{2+}+{\text{Mg}}^{2+}+{\text{Na}}^{+}\right]\right]\times 100 $ <25 Unsuitable Doneen (1975) 25–75 Moderate >75 Suitable MR% $ [({\text{Mg}}^{2+})/{\text{Ca}}^{2+}+{\text{Mg}}^{2+})]\times 100 $ <50 Suitable Paliwal (1976) >50 Unsuitable PS (meq/L) $ {\text{Cl}}^{-}+\dfrac{1}{2}\mathrm{SO}_4^{2-} $ <5 Excellent to good Doneen (1975) 5–10 Good to injurious >10 Injurious to un satisfactory Table 2. Normalized weight (wi) for the IWQI calculation and the parameter threshold values for the quality measurement (Qi) calculation (Meireles et al. 2010; Ayers and Westcot, 1985).
Qi EC (dS/m) SAR (meq/L)1/2 Na+ (meq/L) Cl− (meq/L) HCO3− (meq/L) 85–100 0.20 ≤ EC < 0.75 2 ≤ SAR < 3 2 ≤ Na+ < 3 1 ≤ Cl < 4 1 ≤ HCO3− < 1.5 60–85 0.75 ≤ EC< 1.50 3 ≤ SAR< 6 3 ≤ Na+ < 6 4 ≤ Cl <7 1.5 ≤ HCO3− < 4.5 35–60 1.50 ≤ EC < 3.00 6 ≤ SAR < 12 6 ≤ Na+ < 9 7 ≤ Cl < 10 4.5 ≤ HCO3− < 8.5 0–35 EC < 0.2 or EC ≥ 3.00 SAR < 2 or SAR ≥ 12 Na+ < 2 or Na+ ≥ 9 Cl < 1 or Cl ≥ 10 HCO3− < 1 or HCO3− ≥ 8.5 Weight (wi) 0.211 0.189 0.204 0.194 0.202 Table 3. Water quality index characteristics classification (Meireles et al. 2010)
IWQI Restrictions on water use Recommendation Soil Plant 85–100 No Restriction required (NR) Can be used for the majority of soil types with low probability of causing salinity and sodicity risks, except for soils with extremely low permeability No toxicity risk for most plants 70–85 Low Restriction required (LR) It should be used in light-texture or moderate permeability soils; recommended to avoid its use in soils with high clay levels Avoid salt-sensitive plants 55–70 Moderate Restriction required (MR) May be used in moderate to high soil permeability values of soils Plants with moderate tolerance to salts may be grown 40–55 High Restriction required (HR) May be used in soils with high permeability It can be used for plants with moderate to high salt tolerance 0–40 Severe Restriction required (SR) Should be avoided its use for irrigation under normal conditions Plants with a high tolerance to salt should be irrigated only, except water with extremely low levels of Na+, Cl−, and HCO−3 Table 4. Descriptive statistics of major ions and miscellaneous chemical parameters (unit=mg/L except pH)
Parameters Min Max Mean SD Maximum allowable limit
(Ayres and Westcot, 1985)% above standard pH 7.2 8.2 7.5 0.32 6–9 0 Ca2+ 22 325 86.8 71.1 <400 0 Mg2+ 8 160 43.5 34.1 <60 16 K+ 0.6 22 3.79 5.59 <20 0 SO42− 8.9 99 33.3 22.1 <960 0 Cl− 7.6 74 33.3 6.9 <106.5 0 NO3− 15.2 37.1 20.5 5.4 <30 32 NO2− 0.01 0.18 0.06 0.044 <1.6 0 HCO3− 103.7 433.1 280 98.6 <610 0 NH4+ 0.12 0.45 0.21 0.09 <5 0 PO43− 0.003 1.02 0.14 0.26 <2 0 Table 5. Descriptive statistics and recommended maximum levels of heavy metal concentration in water used for irrigation
Parameters (mg/L) Min. Max. Mean Std. Maximum limit
(Ayers and Westcot, 1985)Samples exceed Standard (%) Fe 0.002 2.38 0.68 0.68 5 0 Cu 0.0009 0.01 0.0033 0.0025 0.2 0 Pb 0.00001 0.016 0.0027 0.0034 5 0 Cr 0.000003 0.012 0.0009 0.002 0.1 0 Zn 0.001 0.6 0.076 0.12 2 0 Ni 0.0012 0.06 0.035 0.374 0.2 0 As 0.0001 0.064 0.0039 0.013 0.1 0 Table 6. Descriptive statistics of irrigation water quality parameters and the calculated indices
Parameters Sample range Min. Max. Mean Std. Standard Range Classification % of samples with standard EC (µS/cm) 306 2,711 1,012.4 647 <250 Excellent 0 250–750 Good 48 750–2,250 Permissible 40 2,250–4,000 Doubtful 12 TDS (mg/L) 195.8 1,735 647.9 414.1 <1,000 Non saline 80 1,000–3,000 Slightly saline 20 3,000–10,000 Moderately saline 0 >10,000 Very saline 0 TH (mg/L) 87.9 1,470.5 395.8 275 <75 Soft 0 75–150 Moderate 8 150–300 Hard 32 >300 Very hard 60 SAR (meq/L) 0.28 3.51 1.33 0.88 <10 Excellent 100 10–18 Good 0 18–26 Doubtful 0 >26 Unsuitable 0 RSC (meq/L) −28.3 9.3 −2 6.95 <1.25 Good 80 1.25–2.5 Medium 4 >2.5 Unsuitable 16 Na% 10.5 57.8 24.8 10 <20 Excellent 40 20–40 Good 56 40–60 Permissible 4 60–80 Doubtful 0 >80 Unsuitable 0 KI (meq/L) 0.11 1.34 0.35 0.24 <1 Suitable 96 >1 Unsuitable 4 PI% 28 89 50.6 15.6 <25 Unsuitable 0 25–75 Moderate 12 >75 Suitable 88 MR% 8.6 71 46 13.7 <50 Suitable 68 >50 Unsuitable 32 PS (meq/L) 0.31 2.8 1.3 0.77 <5 Excellent to good 100 5–10 Good to injurious 0 >10 Injurious to Un satisfactory 0 Table 7. Irrigation water quality index results of water samples
Sample points WiQi (EC) WiQi (SAR) WiQi (Na+) WiQi (Cl−) WiQi (HCO3−) ∑WiQi ∑Wi IWQI Sb1 19.8 3.3 3.6 3.4 16.0 46.1 1 46.1 Db1 18.6 3.3 15.9 3.4 18.9 60.0 1 60.0 Db2 18.7 3.3 18.4 3.4 3.5 47.3 1 47.3 Db3 18.1 3.3 18.0 18.4 3.5 61.3 1 61.3 Sb2 17.5 3.3 19.3 19.2 17.5 76.9 1 76.9 Db4 18.9 3.3 3.6 3.4 3.5 32.7 1 32.7 Db5 18.8 15.6 7.5 18.9 12.2 73.1 1 73.1 Db6 8.4 16.9 3.6 18.9 3.5 51.3 1 51.3 Db7 8.8 18.0 12.0 3.4 3.5 45.7 1 45.7 Db8 10.7 18.0 13.5 3.4 3.5 49.1 1 49.1 Db9 18.2 15.3 14.7 3.4 9.7 61.3 1 61.3 Db10 17.7 3.3 3.6 18.3 12.6 55.5 1 55.5 Sb3 15.9 3.3 3.6 19.2 9.5 51.4 1 51.4 Sb4 18.6 3.3 3.6 3.4 13.3 42.2 1 42.2 Sb5 12.3 3.3 19.1 19.4 10.5 64.5 1 64.5 Sb6 17.4 3.3 3.6 3.4 11.3 39.0 1 39.0 Sb7 16.4 3.3 3.6 3.4 10.0 36.6 1 36.6 Sb8 16.9 3.3 3.6 3.4 10.4 37.5 1 37.5 Sb9 17.8 3.3 3.6 3.4 11.8 39.9 1 39.9 Sb10 13.1 3.3 18.5 18.4 13.1 66.4 1 66.4 Sb11 18.6 3.3 3.6 18.7 12.1 56.3 1 56.3 Sb12 20.0 3.3 3.6 3.4 14.9 45.2 1 45.2 Sb13 20.5 3.3 3.6 3.4 16.8 47.6 1 47.6 Sb14 18.4 3.3 3.6 3.4 11.1 39.7 1 39.7 Db11 11.3 18.9 14.2 19.2 3.5 67.1 1 67.1 -
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