Hydro-geochemical evaluation of groundwater with studies on water quality index and suitability for drinking in Sagardari, Jashore
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Abstract: Sagardari union is facing groundwater crisis because of contaminations from agriculture and urban sewage, which bring a considerable change in water quality. In view of this, hydro-chemical analyses were undertaken on 35 groundwater samples and the following hydro-geochemical parameters, pH, total dissolved solids (TDS), total hardness (TH), electrical conductivity (EC), cations and anions, were analyzed. From the analytical results, it is found that pH value was lower than WHO drinking water standard and the middle-downstream portions of the investigation region show higher EC. The piper plot indicates that the groundwater in Sagardari falls in the categories of NaClHCO3 hydro-chemical facies. Higher TH in groundwater was detected, but still in an acceptable range. In addition, salinity and arsenic ratio are higher and moderately higher, respectively. The spatial distribution of Groundwater Quality Index (GWQI) was determined by geo-statistical modelling of Sagardari union. The study provides information and supports the administration which to make better groundwater utilization and quality control in the Sagardari union.
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Key words:
- Sagardari union /
- Groundwater /
- Hydro-geochemistry /
- Spatial distribution /
- Water quality index
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Table 1. Hydro-geochemical analyses techniques for each parameter
Groundwater properties Progression Temperature Technique of thermometric. Foremost ions with trace constituent Inductively attached with plasma-atomic of discharging spectrometry systematic process. Chlorine Ion selective electrode process. Ions Selective techniques of electrode. pH Technique of thermometric. Conductivity Technique of electrical conductivity. Total dissolved solids Filtration during 0.48 μm filmable filter, remains the filtrate desiccated on temperature 104 ~106℃. Table 2. Parameters of groundwater chemistry with their weight (wi) and relative weight (Wi) considering the range of standard values from World Health Organization
Parameters (mg/L) Weight (Wi) (mg/L) Relative weight (Wi) WHO Permissible Limit(1997, 2002) (mg/L) TDS 4 0.08 1 000 pH 3 0.06 8.5 Chloride 4 0.08 600 Alkalinity 3 0.06 400 Iron 4 0.08 0.3 Arsenic 4 0.08 0.01 Manganese 5 0.10 0.05 Hardness 4 0.08 500 Calcium 4 0.08 200 Magnesium 2 0.04 150 Sodium 3 0.06 200 Bicarbonate 3 0.06 600 Potassium 4 0.08 12 Table 3. Descriptive statistics of hydro-geochemical parameters in groundwater and their comparison with World Health Organization(1997, 2002) standard for drinking water purposes
Parameter Min Max Variance Standard division Average Drinking limit(1997, 2002)(mg/L) TDS (mg/L) 475 3 300 719 471.62 836.01 1 514.28 1 000 Con. of pH 7.74 8.24 0.01 0.12 8.00 8.5 Chloride (mg/L) 157.81 1 890.6 269 961.42 512.10 815.12 600 Alkalinity (mg/L) 340.09 599.9 5 973.39 76.10 454.14 400 Iron (mg/L) 0 0.44 0.44 0.124 0.137 0.3 Arsenic (mg/L) 0.002 0.089 0.0005 0.022 0.018 0.01 Manganese (mg/L) 0 0.111 0.001 0.033 0.041 0.05 Conductivity (uS/cm) 970 6310 2 405 173.67 1 528.54 2 867.6 500 Hardness (mg/L) 200 760 16 753.65 127.52 358 500 Calcium (mg/L) 49 149.66 555.92 23.23 75.42 200 Magnesium (mg/L) 15.21 93.80 315.11 17.49 41.16 150 Sodium (mg/L) 23.09 904.89 59 869.93 241.16 322.76 200 Bicarbonate (mg/L) 28.16 1 103.96 89 110.41 294.21 393.80 600 Potassium (mg/L) 10 25.98 20.09 4.41 18.86 12 Table 4. Ratings of groundwater irrigation quality on the basis of hydro-geochemical parameters such as EC, SAR, SSP, MH, WQI by Richards (Sadashivaiah et al. 2008), Wilcox (Balachandar et al. 2010)
Parameters Range Water class EC < 250 Excellent 250~750 Good 750~2 250 Permissible > 2 250 Doubtful SAR 0~10 Excellent 10~18 Good 18~26 Doubtful > 26 Unsuitable MH < 50 Suitable > 50 Harmful & Unsuitable SSP < 20 Excellent 20~40 Good 40~60 Permissible 60~80 Doubtful > 80 Unsuitable IWQI 85~100 Excellent 70~85 Good 50~70 Permissible 40~55 Doubtful 0~40 Severe Table 5. Classification of groundwater based on WQI in the investigation area
Samples ID WQI Water type S-1 54.40 Good water S-2 61.21 Good water S-3 47.12 Excellent water S-4 51.84 Good water S-5 72.97 Good water S-6 67.37 Good water S-7 86.84 Good water S-8 41.21 Excellent water S-9 52.10 Good water S-10 36.01 Excellent water S-11 44.99 Excellent water S-12 34.22 Excellent water S-13 29.92 Excellent water S-14 94.13 Good water S-15 82.58 Good water S-16 69.75 Good water S-17 38.93 Excellent water S-18 37.96 Excellent water S-19 46.31 Excellent water S-20 50.15 Good water S-21 50.41 Good water S-22 35.35 Excellent water S-23 59.45 Good water S-24 73.83 Good water S-25 32.14 Excellent water S-26 62.83 Good water S-27 104.97 Poor Water S-28 55.89 Good water S-29 87.83 Good water S-30 89.47 Good water S-31 49.32 Excellent water S-32 38.54 Excellent water S-33 101.13 Poor Water S-34 107.70 Poor Water S-35 36.98 Excellent water -
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